When asked by Allure magazine about her dream dinner party, the Oscar winner says: "For sure, we're going to start with the Obamas. The girls can play with my kids."
See photos of kids in the White House!
Also on her list: Oprah Winfrey, George Clooney, Tina Fey, Tom Hanks, Rita Wilson, Diane Sawyer and her husband Mike Nichols.
Roberts says she'd cook "a big chicken tagine with figs and apricots" herself.
The 41-year-old also opens up about staying gorgeous at her age.
"The key to beauty is always to be looking at someone who loves you, really," she said. The actress wed cameraman Danny Moder, whom she met on the set of The Mexican, in 2002.
Check out pictures of celebs who are 40 and fabulous!
She's back to work in thriller Duplicity (out this March) after taking a few years off to raise twins Hazel and Finn, 4, and Henry, 2.
"A lot of the mom struggle in life is that everything happens within the four walls of the home, and it can lose its luster a little bit, maybe," she says of being a stay-at-home mom. "You just have to bring it in from the outside sometimes."
Check out more photos of stars with twins.
But the "coolest thing you can do for your children is to love each other in their presence. I'm the luckiest girl in town, I really am," she says.
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