Musical guests Jay-Z, Kanye West and Rihanna have been previously announced to perform.
See photos of stars goofing off.
The talk show host will also feature a regular segment where celebs get behind the wheel of an electric car and race around a track.
Check out the day's top news photos.
"They can plow into a light post. They could roll the thing. but I've told it to a number of stars, and in fact, even Tom Cruise called and said 'Can I get in there early and practice?'" Leno said at a Television and Critics Association Panel last week. "I said, 'No, nobody gets to practice.'"
Leno's primetime show premieres Sept. 14.
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Did you see Kate Gosselin spoof herself on The Jay Leno Show?
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