And let's face it: The emotions stemming from that split make you either love them or hate them. Regardless, in 2007, more than ever, America couldn't stop watching Jolie, 32, and Pitt, 44, as they juggled two hot careers and went from three kids to four (Pax, 4, joined in March). On children, Pitt recently said, "we're just getting started."
Then, there's the pair's endless humanitarian work: Jolie recently supported her man in New Orleans as he announced plans to build 150 more home there by next summer.
Coming in at second: Tom Cruise and Katie Holmes. Though naysayers thought it wouldn't last, the couple continue to radiate, especially at the sight of little Suri, 20 months. A source tells Us, "Tom is definitely ready for more babies." See how the couple celebrated their first year of marriage here.
For more of Us' Best and Worst of 2007 — including the year in hookups and breakups, surprise pregnancies and Top 10 Meltdowns — grab the new issue, on newsstands now.
Tell Us: Do Brad and Angelina deserve to be Couple of the Year?
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